Law of Thermodynamics
A definite area or space where some thermodynamic process takes place is known as……
Thermodynamics system
Thermodynamic cycles
Thermodynamics process
Thermodynamics law
An open system is one in which….
Heat and work cross the boundary of the system,but the mass of the working substance does not
Mass of working substance crosses the boundary of the system but the heat & work do not
Cannot transfer either energy or mass to or from the surroundings
Is one in which mass within the system is not necessarily constant
An isolated system….
is a specified region where transfer of energy and/or mass take place
is a region of constant mass & only energy is allowed to cross the boundaries
cannot transfer either energy or mass to or from the surroundings
is one in which mass within the system is not necessarily constant
Which of the following is an intensive property of a thermodynamic system
Volume
Temperature
Mass
Energy
In an extensive property of a thermodynamic system
extensive heat is transferred
extensive work is done
extensive energy is utilized
None of the above
Which of the following is the extensive property of a thermodynamic system
Pressure
Volume
Temperature
Density
When two bodies are in equilibrium with the third body they are also in thermal equilibrium with each other. This is called …
zeroth scale of thermodynamics
first law of thermodynamics
second law of thermodynamics
Kelvin Planck's law
The temperature at which the volume of a gas becomes zero is called
absolute scale of temperature
absolute zero temperature
absolute temperature
none of the above
The value of one bar (in SI units) is equal
100 N/m²
1000 N/m²
1×10⁴ N/m²
1×10⁵ N/m²
The absolute zero pressure will be
when molecular momentum of the system becomes zero
at sea level
at the temperature of -273 K
under vacuum conditions
Absolute zero temperature is taken as
-273°C
273°C
237°C
-373°C
Which of the following is correct?
absolute pressure= gauge pressure+ atmospheric pressure
Gauge pressure= absolute pressure + atmospheric pressure
Atmospheric pressure= absolute pressure+ gauge pressure
Absolute pressure= gauge pressure- atmospheric pressure
The unit of energy in SI units is
S Joule (J)
Joule metre (Jm)
Watt (W)
Joule/metre (J/m)
One watt is equal to
1 Nm/s
S 1N/min
10 N/s
100 Nm/s
One joule (J) is equal to
1 Nm
kNm
10 Nm/s
10 kNm/s
The amount of heat required to raise the temperature of 1 kg of liquid state water through 1°C is called
specific heat at constant pressure
specific heat at constant volume
kilo calorie
none of the above
The heating & expanding of a gas is called
thermodynamic system
thermodynamic cycle
thermodynamic process
thermodynamic law
A series of operations, which take place in a certain order & restore the initial condition is known as
reversible cycle
irreversible cycle
thermodynamic cycle
none of the above
The condition for the reversibility of a cycle is
the pressure & temperature of the working substance must not differ, appreciably, from those of
all the processes, taking place in the cycle of operation, must be extremely slow
there should be no loss of energy during the cycle of operation
All of the above
In an irreversible process, there is a
loss of heat
no loss of heat
gain of heat
no gain of heat
The main cause of the irreversibility is
mechanical & fluid friction
unrestricted expansion
heat transfer with a finite temperature difference
all of the above
According to kinetic theory of heat
temperature should rise during boiling
temperature should fall during freezing
at low temperature all bodies are in solid state
at absolute zero there is absolutely no vibration of molecules
A system comprising a single phase is called a
a closed system
open system
isolated system
homogeneous system
A control volume refers to
a fixed region in space
a specified mass
an isolated system
a reversible process only
Internal energy of a perfect gas depends on
temperature, specific heats & pressure
temperature, specific heats & enthalpy
temperature, specific heats & entropy
temperature only
In reversible polytrophic process
true heat transfer occurs
the entropy remains constant
the enthalpy remains constant
the internal energy remains constant
An isentropic process is always
irreversible & adiabatic
reversible & isothermal
frictionless & irreversible
reversible & adiabatic
A reversible process requires that
there be no heat transfer
Newton’s law of viscosity be satisfied
temperature of system & surroundings be equal
there be no viscous or coulomb friction in the system
The first law of thermodynamics for steady flow
accounts for all energy entering & leaving a control volume
is an energy balance for a specified mass of fluid
is an expression of the conservation of linear momentum
is primarily concerned with heat transfer
The characteristic equation of gases pV=mRT holds good for
monatomic gases
diatomic gas
real gases
ideal gases
A gas which obeys kinetic theory perfectly known as
monatomic gas
diatomic gas
Perfect gas
real gas
Work done in a free expansion process is
zero
minimum
maximum
positive
Which of the following is not a property of the system
temperature
pressure
specific volume
Heat
In the polytrophic process equation pvⁿ = constant, if n is infinitely large, the process is termed as
constant volume
constant pressure
constant temperature
adiabatic
The process or systems that do not involve heat are called
isothermal processes
equilibrium processes
thermal processes
Adiabatic processes
In isothermal process
temperature increase gradually
volume remains constant
pressure remains constant
change in internal energy is zero
During throttling process
internal energy does not change
pressure does not change
entropy does not change
enthalpy does not change
When a gas is to be stored, the type of compression that would be ideal is
isothermal processes
adiabatic
polytrophic
constant volume
If a process can be stopped at any stage & reversed so that the system & surroundings are exactly restored to their initial states, it is known as
adiabatic process
isothermal process
Reversible process
frictionless process
The state of a substance whose evaporation from its liquid state is complete, is known as
vapour
perfect gas
air
Steam
In SI units, the value of the universal gas constant is
0.8314 J/mole/k
8.314 J/mole/K
8314 J/mole/K
831.4 J/mole/K
When the gas is heated at constant pressure, the heat supplied
increase the internal energy of the gas
increases the temperature of the gas
does some external work during expansion
both (b) & ( c)
The gas constant ® is equal to the
sum of two specific heats
difference of two specific heats
product of two specific heats
ratio of two specific heat
Second law of thermodynamics defines
Heat
Work
Enthalpy
entropy
For a reversible adiabatic process, the change in entropy is
zero
minimum
maximum
infinite
For any reversible process, the change in entropy of the system & surroundings is
negative
unity
zero
Positive
For any irreversible process the net entropy change of system and surrounding
Zero
Positive
Negative
Infinite
The processes of a Carnot cycle are
two adiabatic & two constant volume
one constant volume & one constant pressure & two isentropies
two adiabatic & two isothermals
two isothermals & two isentropies
Isentropic flow is
irreversible adiabatic flow
ideal fluid flow
perfect gas flow
reversible adiabatic flow
In a Carnot engine, when the working substance gives heat to the sink
the temperature of the sink increases
the temperature of the sink remains same
the temperature of the source decreases
the temperature of the source increases
If the temperature of the source is increased, the efficiency of the Carnot engine
Decrease
increase
does not change
will be equal to the efficiency of a practical engine
The efficiency of an ideal Carnot engine depends on
working substance
on the temperature of the source only
on the temperature of the sink only
On the temperature of the sources and sinks
In a reversible cycle, the entropy of the system
increases
decreases
does not change
first increases & then decreases
A frictionless heat engine can be 100% efficient only if its exhaust temperature is
equal to its input temperature
less than its input temperature
0°C
0°K
Kelvin-Plank's law deals with
conservation of energy
conservation of heat
conservation of mass
conversion of heat into work
Which of the following statements is correct according to Clausius statement of second law of thermodynamics?
it is impossible to transfer heat from a body at a lower temperature to a body at a higher temperature
it is impossible to transfer heat from a body at a lower temperature to a body at a higher temperature, without the aid of an external source
it is possible to transfer heat from a body at a lower temperature to a body at a higher temperature by using refrigeration cycle
none of the above
According to Kelvin-Planck's statement of second law of thermodynamics
it is impossible to construct an engine working on a cyclic process, whose sole purpose is to convert heat energy into work
it is possible to construct an engine working on a cyclic process, whose sole purpose is to convert the heat energy into work
it is impossible to construct a device which while working in a cyclic process produces no effect other than the transfer of heat from a colder body to a hotter body
None of the above
The property of a working substance which increases or decreases as the heat is supplied or removed in a reversible manner is known as
enthalpy
internal
energy entropy
all of the above
The entropy may be expressed as a function
pressure & temperature
temperature & volume
heat & work
all of the above
The change of entropy when heat is absorbed by the gas is
Positive
Negative
positive or negative
all of the above
Which of the following statements is correct?
the increase in entropy is obtained from a given quantity of heat at a low temperature
the change in entropy may be regarded as a measure of the rate of the availability of heat for transformation into work
the entropy represents the maximum amount of work obtainable per degree drop in temperature
all of the above
The condition for the reversibility of a cycle is
the pressure & temperature of the working substance must not differ, appreciably, from those of the surroundings at any stage in the process
all the processes taking place in the cycle of operation must be extremely slow
the working parts of the engine must be friction free
all of the above
In an irreversible process, there is a
loss of heat
no loss of work
gain of heat
no gain of heat
The main cause of the irreversibility is
mechanical & fluid friction
unrestricted expansion
heat transfer with a finite temperature difference
all of the above
The efficiency of the Carnot cycle may be increased by
increasing the highest temperature
decreasing the highest temperature
increasing the lowest temperature
decreasing the lowest temperature
Which of the following is the correct statement?
all the reversible engines have the same efficiency
all the reversible & irreversible engines have the same efficiency
irreversible engines have maximum efficiency
all engines are designed as reversible in order to maintain maximum efficiency
The reversible engines are
least efficient
most efficient
having same efficiency as irreversible engines
none of the above
Gases could have an infinite number of specific heats but only ……. Specific heats are defined
One
two
three
four
Which one of the following statements is correct?
pressure is an extensive property
Density is an intensive property
density is an extensive property
temperature is an extensive property
First law of thermodynamics deals with conservation of
mass
movements
energy
Heat
The area under the T-s (temperature - entropy) curve of any thermodynamic process represents
heat rejected only
heat absorbed only
work done during the process
heat absorbed or reject
Second law of thermodynamics defines
Work
Heat
Entropy
internal energy
Which one of the following processes or systems does not involve heat
steady processes
isothermal processes
adiabatic processes
thermal processes
For storing a gas which one of the following types of compression will be ideal
constant volume
polytrophic
Adiabatic
isothermal
A process which can be stopped at any stage & reversed so that the system & the surroundings are exactly restored to their thermodynamic process irreversible process reversible process isothermal process C initial states is known as
thermodynamic process
irreversible process
reversible process
isothermal process
Thermodynamic equilibrium is completely defined by the specification of
generalized displacements
internal energy
Enthalpy
all of the above
Which of the following is heterogeneous system?
cooking gas in a cylinder
atmospheric air
a mixture of ice, water & steam
a mixture of hydrogen & oxygen
Which one of the following gases obeys kinetic theory perfectly?
perfect gas
pure gas
monoatomic gas
diatomic gas
………. Is not a property of the system
pressure
temperature
heat
specific volume
In which of the following processes the external work done is not zero?
throttling
free expansion
constant volume process
constant pressure process
The extension & compression of a helical spring is an example of
irreversible process
reversible process
isothermal process
adiabatic process
In all irreversible processes, the entropy of the system
remains unaltered
reduces to zero
increases
none of the above
Due to which of the following reasons food can be cooked quicker in a pressure cooker?
it is made of a metal
steam remains within the cooker
high pressure steam has a high temperature
none of the above
Which of the following is a reversible process?
throttling
combustion
free expansion
extension & compression of spring
Leaking of air from a punctured tube is an example of
isothermal expansion
adiabatic expansion
throttling
constant pressure expansion
Temperature of a gas is produced due to which of the following?
attraction of molecules
repulsion of molecules
kinetic energy of molecule
all of the above
The same volume of all gases would represent their
specific gravity
densities
specific weights
molecular weights
To convert volumetric analysis to gravimetric analysis, the relative volume of each constituent of the flue gases is
divided by its specific weight
multiplied by its density
multiplied by its molecular weight
divided by its molecular weight
First law of thermodynamics gives relationship between which of the following?
heat & internal energy
heat &work
Heat work and properties of the system
Various thermodynamic processes
The temperature in a process in which work is done by expanding a gas under adiabatic condition will
Decrease
increase
first decrease & then increase
remain unaltered
On which of the following laws measurement of temperature is based?
joule's law
zeroth law of thermodynamics
first law of thermodynamics
second law of thermodynamics
The perpetual motion of the first kind is represented by which of the following?
a machine that continuously creates its own energy
an engine with 100 percent efficiency
a fully reversible engine
none of the above
Which of the following statements regarding a perpetual motion machine is correct?
it is an in efficient machine
it is non-thermodynamic machine
it is thermodynamic machine
it is hypothetic machine whose operation would violate the laws of thermodynamics
Which of the following statement regarding a property of system, is correct?
it is path function
it is a point function
it is always of intensive type
none of the above
……….. Is an intensive property
specific volume
total volume
total mass
total energy of a system
Which of the following processes undergoes energy loss due to friction?
reversible process
irreversible process
isentropic process
adiabatic process
A system is said to be in thermodynamic equilibrium if it is in
chemical equilibrium
thermal equilibrium
mechanical equilibrium
all of the above
Which of the following statements is correct?
irreversible engines have maximum efficiency
all the reversible engines have same efficiency
all the reversible engines working between the same temperature limit have the same efficiency
all the engines have same efficiency
Kelvin Planck's law deals with conservation of
Work
Heat
work into heat
heat into work
A thermodynamic process will be reversible when the temperature difference between hot body & working substance is
minimum
maximum
infinity
Zero
The basis for measuring thermodynamic property of temperature is given by …….Law of thermodynamics
Zeroth
first
Second
third
As differentials, heat & work would be described mathematically as
Exact
Inexact
point function
discontinuity
Which of the following is an open thermodynamic system?
pressure cooker
manual ice cream freezer
centrifugal pump
none of the above
……… is a non-quasistatic process
free expansion of gas
expansion of gas in a cylinder under constant pressure
rapid leakage of air from a bicycle tyre
gradual compression of gas inside a piston-cylinder arrangement
107) heat engine receives heat at the rate of 1500 kJ/min. & gives an output of 8.2 kW. Its thermal efficiency is equal to
20.50%
30.20%
32.80%
44.60%
An inventor claims that a new heat cycle will develop 0.4 kW for a heat addition of 3 2.5 kJ/mm. The temperature of heat source is 1990 K & that of sink is 850K. Is his claim true?
TRUE
FALSE
either of the above
unpredictable
Consider the following statements: The definition of 1. temperature is due to zeroth law of thermodynamics 2.entropy is due to first law of thermodynamics 3.internal energy is due to second law of thermodynamics 4 reversibility is due to Kelvin-Planck's statement of these statements
.1,2 & 3 are correct
1,3 & 4 are correct
1 alone is correct
2 alone is correct
A heat engine is supplied with 250 kJ/s of heat at a constant fixed temperature of 227°C. The heat rejected at 27°C. The cycle is reversible, if the amount of heat rejected is
273 kJ/s
200 kJ/s
180 kJ/s
150 kJ/s
A Carnot engine receiving heat at 400K has an efficiency of 25%. The C.O.P. of a Carnot refrigerator working between the same temperature limits is
1
2
3
4
If a heat engine gives an output of 3 kW when the input is 10,000 J/s, then the thermal efficiency of the engine will be
20%
30%
70%
76.70%
The fundamental unit of enthalpy is
MLT ˉ²
ML²Tˉ¹
ML²T ˉ²
ML³T ˉ²
In a cyclic heat engine operating between a source temperature of 600°C & a sink temperature of 20°C, the least rate of heat rejection per kW net output of the engine is
0.460 kW
0.505 kW
0.588 kW
0.650 kW
In a reversible cycle the source temperature is 227°C & the sink temperature is 27°C. The maximum available work for a heat input of 100 kJ will be
100 kJ
60 kJ
40 kJ
88 kJ
A heat engine using lake water at 12° C as source & the surrounding atmosphere at 2°C as sink executes 1080 cycles per min. If the amount of heat drawn per cycle is 57J, then the output of the engine will be
66 W
56 W
46 W
36 W
One reversible heat engine operates between 1600 K & T₂ K & another reversible heat engine operates between T₂ K & 400 K. If both the engines have the temperature T₂ must be equal to
100 kJ
1200 K
1400 K
800 K
An engine receives 15152 J/s of heat & produces 5 KW of power. The efficiency of the engine is
25%
27.50
30%
33%
Choose the correct statement
pressure, temp and entropy are extensive property
pressure ,temp and entropy are intensive property
pressure ,volume ,temp and entropy are extensive property
volume and entropy are extensive property
The second law of thermodynamics defines
heat
enthalpy
internal energy
entropy
The first law of thermodynamics defines
Entropy
internal energy
work
Heat
Which law of thermodynamics defines entropy
First
second
third
zeroth
A process becomes irreversible due to
work performed by the system work
performed upon the system
heat supplied to the system
friction in the system
Which of the following processes is essentially irreversible
Isothermal
adiabatic
Isentropic
throttling
A thermodynamic cycle operates between 400 K. & 290 K. 500 MJ/s of heat is added to the working substance. The power generated is
290 MW
290 MJ
137.5 MJ
137.5 MW
A reversible engine performing as engine has efficiency of 62.5%. If it is reversed to work as refrigerator its COP will be
60%
62.50%
65%
37.50%
A reversible engine performing as refrigerator has COP=33%. If the same machine operates as engine, its efficiency will be
67%
33%
75%
37.50%
The amount of heat absorbed by a system at lower temperature is
coefficient Of performance
efficiency
work supplied
refrigerating effect